The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and solid:liquid ratios has been studied. The ...
Extraction and separation of vanadium and nickel from fly ash produced in heavy fuel power plants. Chemical Engineering Journal 2011, 173 (1), 191-197. …
Vanadium as a rare element has a wide range of applications in iron and steel production, vanadium flow batteries, catalysts, etc. In 2018, the world's total vanadium output calculated in the form of metal vanadium was 91,844 t. The raw materials for the production of vanadium products mainly include vanadium-titanium magnetite, …
Fly ashes resulting from the combustion of fuel containing high concentrations of vanadium that can be slightly removed by water and more efficiently …
DOI: 10.2139/ssrn.3954870 Corpus ID: 244057799; Vanadium Extraction from Stone Coal Using a Novel Two-Stage Roasting Technology @article{Tang2022VanadiumEF, title={Vanadium Extraction from Stone Coal Using a Novel Two-Stage Roasting Technology}, author={Zhidong Tang and Zhenya Zhou and Jia Xu Jin and Yong-sheng …
Anionic resins react with and separate pentavalent vanadate ions "V(V)" from other impurities in aqueous solutions, but chelating resins are used to extract V(IV) from acidic solutions. 80,88 Although there are several papers on using ion exchange resins for the separation of vanadium ions from other impurities in various media, the ...
Vanadium and nickel are concentrated in some kind of ash in carbonate forms and converted to high purity salts and then oxides with extraction and crystallization. The general scheme of vanadium and …
The general scheme of vanadium and nickel extraction from fly ash is shown in Figure 6. 5.5. Pyrometallurgical Methods. Pyrometallurgical approaches [119,120,121,122] are qualitatively different from sintering with salts or controlled oxidation; their product are alloys of the target metals with a less expensive metal, usually Fe.
The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and solid:liquid ratios has been studied. The prepared Boiler ash–NaCl mixture has been roasted in the temperature range 700–1000 ℃, and then, the obtained roast has been leached using …
For instance, in 1987–1990, GRES-19 alone shipped 300 tons of ash waste for the extraction of vanadium . The rich ash was used to produce ferrovanadium. The technological properties of ash and fuel oil slag, taking into account the processing experience and data published by other authors, imply that this type of raw material can …
Vanadium remains in the raffinate, which is fed into a second solvent extraction circuit. There vanadium in turn is extracted in the organic phase, stripped with a 10 percent soda ash solution, and precipitated with ammonium sulfate. The ammonium metavanadate precipitate is filtered, dried, and calcined to V 2 O 5.
Petcoke generated during bitumen upgrading is a potential source of vanadium for the global market. Recovering vanadium from the fly ash originating from the combustion of petcoke appears to be a suitable route for commercial implementation, given its high extraction rate. Although the technical feasibility of the recovery process has been …
However, the extraction percentage should be evaluated in the context of bulk V content in the leached material; for example, 80% V leached from 3990 ppm in asphaltite ash provide more V than recovery …
The distribution of vanadium in fly ash became more scattered, and the leaching of vanadium in fly ash was easier than that in stone coal. In order to extract vanadium from fly ash, some leaching agents such as sulfuric acid, hydrochloric acid, alkali and ammonia could be used to dissolve the unsolvable vanadium compounds.
The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and solid:liquid ratios has been studied. The ...
The waste sludge was chemically activated after pyrolysis which could adsorb efficiently 1196 m 2 /g of vanadium (V). Extraction and separation of vanadium and nickel from fly ash (FA) produced in ...
Vanadium: Extraction, Manufacturing and Applications offers systematic coverage of the state-of-the-art in research and development of vanadium. ... coal ash, and meteorites. The sun's spectral lines also indicate the presence of vanadium. Select Chapter 4 - Extraction of vanadium from titanoferrous magnetite: mineral processing and ...
The possibility of extracting vanadium from various carbon materials (petroleum coke, bitumen, fuel-oil ash and slag, ash from foundry graphite, black shale, and lignite) is investigated. Systems for producing vanadium slag from ash and from titanomagnetite ore are compared. The two types of slag are compared in terms of …
Fly ashes resulting from the combustion of fuel containing high concentrations of vanadium that can be slightly removed by water and more efficiently by alkaline or acid solutions. This uncontrolled release can contaminate water sources and requires appropriate storage of fly ashes. This study investigated the possibility of cleaning the …
In order to reduce the environmental impact due to land disposal of oil fly ash from power plants and to valorize this waste material, the removal of vanadium was investigated using leaching processes (acidic and alkaline treatments), followed by a second step of metal recovery from leachates involving either solvent extraction or …
Vanadium extraction from fly ash. Fly ash specifically refers to the soot collected after burning fuel and coal, which is enriched with vanadium and can be used as a source of vanadium. Fly ash is generally treated by leaching with water, alkali, or acid solutions, where vanadium is separated from other impurities. ...
This research mainly focuses on the recovery of vanadium from oil fly ash by carbon removal and the roast-leach process. The oil fly ash contained about 85% …
In this investigation, recovery and separation of nickel and vanadium from leach liquors of power plant fly ash were investigated by solvent extraction using D2EHPA, Cyanex 272, and their mixtures in…
The effect of roasting and leaching variables on vanadium extraction from boiler ash, such as roasting temperatures, NaCl dosages, roasting time, and solid:liquid ratios has been studied. The ...
This framework was used to perform a life cycle GHG emissions assessment of a water leaching and salt roasting process to extract vanadium from fly ash.
Extraction of Vanadium from Athabasca Tar Sands Fly Ash C. O. GOMEZ-BUENO, D. R. SPINK AND G. L. REMPEL The production of refinery grade oil from the Alberta tar sands deposits as currently ... The GCOS fly ash has a larger vanadium concentration than most known commerical vanadium mineral deposits and this fact …
The extraction of V and Ni from a petroleum coke ash (PCA) by pyro- and hydro-metallurgical methods, including roasting in the absence of additive and H 2 SO 4 …
Three different steps, such as carbon burning, salt roasting, and water leaching, were conducted to extract vanadium from the oil fly ash. First, a vanadium …
For each experiment, 1.00 g of coal fly ash was thoroughly mixed with 0.50 g of Na 2 CO 3, then transferred to ceramic crucibles and treated in a furnace for two hours at 850 • C in order to ...
Recycling process of fly ash generated from oil burning. Materials Transactions 42, 2465–2471. Miura, K., Nozaki, K., Isomura, H., Hashimoto, K., Toda, Y., 2001b. Leaching and solvent extraction of vanadium ions using mixer-setllers for the recovery of the vanadium component in fly ash derived from oil burning.
The results obtained showed that, to extract vanadium with amines, it was necessary to work at pH 2 and oxidize, because vanadium in the ashes is essentially in a reduced state. 3 4 pH Raffinate Figure 1 Effects of amine type and acidity on vanadium extraction Extraction results are based on 10 min bath shaker tests made using equal …
The remaining 11% comes from processing the vanadium-bearing oil supply [6-8]." Zhang et al (2021) claim that "nearly 88% of vanadium in the world is extracted from vanadium-titanium magnetite deposits" Zhang et al, 2021. Extraction of vanadium from low-vanadium grade magnetite concentrate pellets with sodium salt. …
The current research examined the extraction of germanium, vanadium, and lithium from coal fly ash (CFA) using a sequential sodium salt roasting and organic acid leaching process. To this end, three sets of experiments were performed. In all experiments, CFA was roasted with salt at 850 °C and then leached with an organic acid.
Although the recovery of vanadium from petroleum ash is a well established commercial practice, it is shown in the present work that such processes are not suitable for recovery of vanadium from the GCOS fly ash. ... H. Ottertun and S. Strandell:Solvent Extraction of Vanadium (IV) with D2EHPA and TBP, International Solvent Extraction Conference ...
The sintering in high Al, Si ash also affects vanadium extraction using sulfuric acid . On the other hand, roasting the slag with NaOH and leaching it with water maximizes vanadium recovery at close to at a roasting temperature over 600 °C .
The uranium and vanadium are separated from the liquid by solvent extraction followed by a liquid-liquid ion exchange process which separates the uranium leaving the vanadium in the acid solution. This is subsequently oxidised and removed from the organic salts with soda ash. Vanadium polyvanadate is precipitated by the addition ammonium sulphate.